California senators push for ban of MTBE Gas additive which forced  the closure of water supply systems
By Stephan Archer
© 1999

SACRAMENTO, Calif -- State senators plan to protest the use of MTBE and to persuade Gov. Gray Davis to ban the gasoline additive that has caused the closure of dozens of drinking water supply systems throughout the state.

Methyl tertiary butyl ether (MTBE) was first introduced into Californians' gas tanks in the early and mid-1990s in an effort to lower car emissions and reduce air pollution. But since its introduction in the state, more than 10,000 wells, lakes and reservoirs have been polluted with the substance.

Sen. Tim Leslie, R-Tahoe City, along with his colleagues, Sen. Dick Mountjoy, R-Arcadia, Sen. Don Perata, D-East Bay, and others will be meeting on the south steps of the state Capitol next Tuesday to rally
for an immediate ban of MTBE. All three senators are currently carrying legislation to make MTBE use unlawful in California.

Leslie's legislation, Senate Bill 272, says, in part, it would "make it a misdemeanor for any person to sell gasoline containing MTBE." It also makes the following statements about MTBE:

•MTBE is highly soluble in water and will transfer readily to groundwater.

•MTBE is capable of contaminating water resources faster than any other gasoline component and has been detected in California's drinking water wells, groundwater, and surface water.

•It is clear that California is placing its limited water resources at risk by using MTBE in gasoline.

•MTBE is an animal carcinogen with the potential to cause cancer in humans.

•MTBE jeopardizes the safety and availability of California's water supply and is clearly a public health threat.

•The cost of treating MTBE-contaminated drinking water sources in California could have a severe impact on state funds.

Leslie's bill also states that studies have shown that no significant air quality benefit has been found in the use of MTBE.

"A recent University of California study concluded that MTBE provides no significant benefit to air quality yet has the potential to cause great harm to our state's water supply," said Leslie. "Common sense dictates
that we take immediate and necessary measures to protect the quality of our state's drinking water and the health of Californians. MTBE must go."

The study being referred to is one the University of California was directed to conduct after former California Gov. Pete Wilson signed into law Mountjoy's Senate Bill 521 Oct. 8, 1997. This bill enacted the MTBE
Public Health and Environmental Protection Act of 1997.

Leslie said that next week's rally will also coincide with a public hearing at the Sacramento Convention Center where the California Environmental Protection Agency will hear testimony pertaining to MTBE.
The state's governor must decide whether or not to prohibit MTBE use in California within 10 days of the public hearing. Currently, the governor has no official position on the issue.

It is Leslie's hope that the rally and the public hearing will encourage the governor to ban, or phase out, MTBE. If he doesn't, Leslie and others plan to move forward with their bills to ban the substance.

"Kick MTBE out of California, and do it now!" exclaimed Leslie.  Besides California, other states -- including Connecticut, Maine, New Hampshire and New York -- have proposed legislation that would ban MTBE.
In Alaska and part of Montana, MTBE has already been banned due to motorists' complaints of health problems including sore throats, nausea  and trouble with breathing. North Carolina also banned MTBE, but the state's action was due to the additive's classification as a probable carcinogen in people.

Besides being detected in the California water supply, MTBE has also been found in 137 water supplies across New Hampshire, dozens of wells in Connecticut and various other water supplies across the U.S. In
Texas, for example, some state and local officials are concerned that MTBE pollution in their state's water supply may force them to shut down some of the water wells in their state.



•High cost of controversial gas additive •Why California mandated poison in your tank

JULY 18, 1997

MTBE High cost of controversial gas additive MTBE doesn't clean air, has negative effects
By Stephan Archer
Copyright 1997

Although gasoline addictive MTBE is now being mandated in fuel sold all over the United States to reduce harmful emissions, leading scientists agree that, in reality, the only thing it is reducing is the amount of
green stuff in consumers' pocketbooks.

Dr. Joel Kauffman, professor of chemistry at the Philadelphia College of Pharmacy and Science, says MTBE seems to have little or no effect in reducing carbon monoxide emissions. The reason? No oxygenate can clean
the air, according to Kauffman, because cars are now equipped with oxygen sensors and catalytic converters that regulate the amount of the engine.

"There's no way that an oxygenate can fool a modern engine into burning cleaner," Kauffman said.

Kauffman added that with oxygenated gasoline, people are now paying more money for gas because oxygen, which engines naturally take freely from the air, is now being added to gasoline at a cost to the consumer. He
also stated that the increase in oxygen in fuel is what is causing the decrease in gas mileage because less of what you fill up with is actually gasoline.

Worse yet, says Dr. Myron Mehlman, editor of the journal Toxicology and Industrial Health, MTBE does not help clean the air.

"There is no evidence that MTBE is helpful to the environment," he states unequivocally.

So why has the federal government approved the use of MTBE? The Environmental Protection Agency oxygenate sees things differently.

"MTBE is not supposed to clean the air," says Dave Kortum, group manager in the Environmental Protection Agency's Department of Fuels and Energy. "We would prefer that there was no MTBE in the air -- just carbon,
oxygen, nitrogen and carbon dioxide which is what the air is made of, but adding MTBE to gasoline would be changing the composition of gasoline in such a way that NOx [nitrogen oxides] emission and VOC [volatile organic compounds] emissions are positively effected, and that does help the air."

Kortum concedes that the issue of reduced carbon monoxide emissions, which is supposed to be a function of MTBE in reformulated gasoline, is one in which there is currently a lot of disagreement.

And there's plenty of disagreement from the experts. Kaufman, for instance, says MTBE is actually increasing NOx emissions making it harder for cars to pass smog checks and, thus, costing the consumer more
to get their cars fixed. Kauffman also said that MTBE itself is a VOC which, when mixed with NOx, helps produce ground-level ozone.

Dr. Peter Joseph, professor of Radio logic Physics at the University of Pennsylvania School of Medicine, says federal and state governments are missing the point by mandating oxygenates such as MTBE.

"I really think that CO [carbon monoxide] is being greatly exaggerated in terms of its ability to do harm at its present level." He thinks something else, possibly formic acid, which he believes may actually be
produced from fuels with MTBE, is the real problem. Formic acid is known to be extremely irritating to the respiratory system.

The EPA's Kortum also concedes that MTBE is leeching into the water supply as many critics have charged.

"We recognize that's a real problem, and a lot has to be done there to address this problem," he said.

JULY 25, 1997


MTBE Why California mandated poison in your tank In name of environment,
known carcinogen added to gas
By Stephan Archer
Copyright 1997

SACRAMENTO -- The California Air Resources Board ignored warnings from the Environmental Protection Agency that gasoline additive MTBE might be carcinogenic before requiring it in every gas tank in the state.

Since the passage of the state man date last summer, MTBE has been used across California as an additive in gasoline to oxygenate the fuel for "cleaner burning." Yet, there is no proof the additive, which is now
being used in many other states, results in reduced air-pollution levels.

"At the time that the regulation was passed, I think that we were aware that it might be carcinogenic and that it could have some other health effects," recalled Dr. Andrew Wortman, the engineer-scientist of the
California Air Resources Board from 1983 until January of 1994. He later added, however, that the board never thought that levels of MTBE in the environment would ever reach a point that would adversely affect
people's health. Wortman also stated that he thought that the board knew even before MTBE usage became mandatory in the state that the chemical wasn't healthy for people.

According to Wortman, the main reason that the California Air Resources Board passed the resolution was because of political pressure.

"This thing was rigged from the first time that it was mentioned," he said. "The chair kept banging on me that the governor insisted on passing it."

The chairwoman at the time was Jananne Sharpless. According to Wortman, Sharpless, one of the few people on the board reappointed by Gov. Pete Wilson, was given a position on the Energy Commission by the governor as an award for her efforts in getting the MTBE resolution passed.

To help get the resolution passed, the Air Resources Board picked favorable data supporting MTBE and threw out the rest, said Wortman. "The Air Resources Board staff selectively threw out all the data they
didn't like," Wortman said.

One of the main ingredients of MTBE, isobutylene, is a by-product of refined crude oil. Referring to isobutylene, Dr. Myron Mehlman, an adjunct professor of public health at the Robert Wood Johnson Medical
School and editor of Toxicology and Industrial Health, said the stuff wasn't worth much by itself but when used to make MTBE, its value increased. "There is a big economic advantage in using isobutylene to make MTBE," Mehlman said.

The economic advantage, according to Wortman, is that the chemical is cheap because it is a by-product of refined oil. Thus, processing it into MTBE would also be cheap, saving the oil companies a significant
amount of money. Wortman pointed out there was one problem with the plan to save money by
using isobutylene to make MTBE. It would cost oil companies an estimated $5 billion to redesign refineries for the production, and all but one of the oil companies in California were, at first, against its use.

The one company in favor of the plan was Atlantic Richfield Company. It didn't cost ARCO anything because the company already had the facilities to make MTBE. In fact, it was ARCO which gave the California Air
Resources Board its reformulated gas as a surrogate for testing emissions.

"ARCO was lying on their side that it was such a wonderful thing and that it would finally clean up the air," Wortman said. "They didn't have a shred of true scientific evidence, though. They just had a cheaper way
of making gasoline than anybody else."

In Sacramento, many legislators are concerned about the lack of research done concerning MTBE's effects on the environment and people. Some officials, including Sen. Richard Mountjoy, R-Arcadia, are even
attempting to rid the state of MTBE. In Senate Bill 521, which he and others brought to the floor of the state Senate Feb. 24, he asked that MTBE be banned from the state of California.

Since the bill's introduction, however, it has been amended beyond Mountjoy's recognition. Among other things, the revised legislation would require a lengthy study of MTBE and postpone indefinitely any ban
on the chemical. The amended bill would also take away the responsibility of cleaning up the chemical from those who produced it and hand it over to the taxpayers.

Mountjoy wants an immediate ban of the chemical in California and wants the oil industry to take responsibility for cleaning up the state. Various doctors from around the nation, oil companies, water districts,
and utility districts have researched MTBE and looked into the dangers which Mountjoy and others are concerned about. Here is what they found.

According to a state Air Resources Board official, the reformulated gas cut smog-forming emissions by 14 percent and cut benzene emissions by 50 percent, which, therefore, cut gasoline's can cancer risk by 30 percent.

However, in a letter to Sen. Mount joy, Dr. Michael Lambert of San Jose State University said, "MTBE actually causes a slight increase in nitrogen oxide, which is the m major component of smog. ... This clearly
demonstrates that MTBE is causing significantly more harm than good." Besides releasing more nitrogen oxide into the air, MTBE emissions release other dangerous chemicals into the air. In his letter to Mountjoy, Lambert pointed out, "MTBE significantly increases two of three known hazardous organic compounds, which are carcinogenic and known to cause and exacerbate respiratory illnesses." These organic compounds are known as aldehydes and ketenes. One of the better known aldehydes which MTBE emissions release into the air is formaldehyde.

MTBE can't reduce smog because, along with fuel injection, most cars since 1984 had an additional device installed in their exhaust manifold called an oxygen sensor. The oxygen sensor regulates the amount of gas
to be released by the injectors so that a cleaner burn will result. Dr. Joel M. Kauffman, a professor of chemistry at Philadelphia College of Pharmacy and Science, said that these oxygen sensors "will hold the concentrations of the usual pollutants to fixed (and desirably low) levels regardless of the composition of the gasoline."

MTBE gets into our rivers, lakes, reservoirs, and groundwater many different ways including precipitation (from air pollution), storm water runoff, surface spills such as at gas stations, and leaks of underground storage tanks and pipes. Once in the water, it is hard to remove it because it is highly soluble. According to an executive summary from Mountjoy's office, MTBE has been found in California's drinking water, including places such as Santa  Monica, Marysville, a private water well in Elmira, and South Lake Tahoe wells.

MTBE has also been found in many reservoirs across the state including Shasta Lake, Anderson reservoir (Santa Clara Valley Water District), Modesto Reservoir, Castaic Lake, San Pablo reservoir (San Francisco Bay Area), and Lake Havasu.

Other authorities report that MTBE has been found in drinking water. A California Environmental Protection Agency report states the following: "As of June 6, 1996, five major oil companies submitted MTBE residue
data for a total of 245 sites in 24 counties. About 76 percent of the sites reported detectable MTBE in one or more monitoring wells."

Walt Wadlow, assistant general manager of the Santa Clara Water District said there is no biological or chemical breakdown of MTBE in water and it migrates at the speed of groundwater. This means that although MTBE is being discovered largely in shallow groundwater reservoirs, it could easily be found in deep wells and springs as well.

Those who have been exposed to MTBE through contact with gasoline have complained of extreme headaches, vomiting, diarrhea, fever, cough, muscle aches, sleepiness, disorientation, dizziness, and skin and eye irritation. There is evidence that MTBE may also cause cancer in humans.

"MTBE causes the same cancers at the same levels in laboratory animals as benzene, a known human carcinogen," said Mehlman, who later concluded that MTBE is, therefore, a probable human carcinogen.

In a letter to Carol Browner of the EPA during December of 1996, Mehlman wrote about the possible human carcinogenic effects of MTBE in water. "MTBE in water poses a risk of death from various cancers, and
therefore, exposure to this dangerous chemical should be avoided in order to avoid needless and preventable cancer risk to humans," he said. Mehlman also said that MTBE contamination in water causes all kinds of neurological illnesses and can also form rashes on the surface of the skin.

Asthma is a health problem that seems to be aggravated by MTBE pollution. Although the EPA reports that incidents of asthma have decreased, Dr. Peter Joseph, professor of Radiologic Physics at the University of Pennsylvania School of Medicine, says they have actually increased by 50 to 100 percent. The asthma incidents, Joseph said, began to increase after 1979 when MTBE was first used at smaller levels.

Because of such potential health hazards, some areas of the country are taking action. For example, Alaska discontinued the use of MTBE in its gasoline. North Carolina also discontinued use of the additive.

But health is not the only concern. According to a Chevron technical bulletin, there is a potential for fuel leaks in cars. Texaco reported the same thing.

"In a very small percentage of older, high-mileage vehicles, it is possible that RFG [reformulated gas] could cause changes to rubber components in certain engines that may result in fuel leaks," an These fuel leaks can result in an increase in car fires. Alex Bess, a Santa Clara mechanic who has seen more repairs where gas lines and seals have to be replaced told the Associated Press that these leaks are dangerous. "The whole engine can catch fire," he said.

Mehlman has one other major concern. He says MTBE has been known to cause drowsiness in drivers.